Issue 2, 2003
From the journal:

Chemical Communications

Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers: Chatt and Wilkins—50 years on

Jeremy N. Harvey,*a   Katie M. Heslop,a   A. Guy Orpena  and  Paul G. Pringlea  

* Corresponding authors

a University of Bristol, School of Chemistry, Cantock′s Close, Bristol
E-mail: jeremy.harvey@bris.ac.uk

Abstract

DFT computations reveal that cis-trans preferences in [PtX2(PR3)2] species are due to a combination of electrostatics, π-backbonding, antisymbiosis, and solvation effects.

Graphical abstract: Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers: Chatt and Wilkins—50 years on

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Article information

DOI
https://doi.org/10.1039/B210939E
Article type
Communication
Submitted
06 Nov 2002
Accepted
10 Dec 2002
First published
20 Dec 2002

Chem. Commun., 2003, 278-279

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Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers: Chatt and Wilkins—50 years on

J. N. Harvey, K. M. Heslop, A. G. Orpen and P. G. Pringle, Chem. Commun., 2003, 278 DOI: 10.1039/B210939E

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