Issue 4, 2003

Liquid clathrate formation in ionic liquid–aromatic mixtures

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate–benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2∶1 inclusion compound.

Graphical abstract: Liquid clathrate formation in ionic liquid–aromatic mixtures

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2002
Accepted
02 Jan 2003
First published
21 Jan 2003

Chem. Commun., 2003, 476-477

Liquid clathrate formation in ionic liquid–aromatic mixtures

J. D. Holbrey, W. M. Reichert, M. Nieuwenhuyzen, O. Sheppard, C. Hardacre and R. D. Rogers, Chem. Commun., 2003, 476 DOI: 10.1039/B212726A

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