Issue 10, 2003
From the journal:

Chemical Communications

Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes†

Yongzhong Bian,a   Rongming Wang,a   Jianzhuang Jiang,*a   Chi-Hang Lee,b   Jinzhi Wangb  and  Dennis K. P. Ng*b  

* Corresponding authors

a Department of Chemistry, Shandong University, Jinan 250100, China
E-mail: jzjiang@sdu.edu.cn

b Department of Chemistry, The Chinese University of Hong Kong, Shatin, N.T., Hong Kong, China
E-mail: dkpn@cuhk.edu.hk

Abstract

Treatment of MIII(Pc)(acac) (M = Sm, Eu, Gd; Pc = phthalocyaninate; acac = acetylacetonate), generated in situ, with 3-(3-pentyloxy)phthalonitrile in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in n-pentanol affords racemic mixtures of the chiral double-deckers MIII(Pc)[Pc(OC5H11)4] [Pc(OC5H11)4 = 1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninate], which have been spectroscopically and structurally characterised.

Graphical abstract: Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes

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DOI
https://doi.org/10.1039/B301139A
Article type
Communication
Submitted
29 Jan 2003
Accepted
27 Mar 2003
First published
17 Apr 2003

Chem. Commun., 2003, 1194-1195

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Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes

Y. Bian, R. Wang, J. Jiang, C. Lee, J. Wang and D. K. P. Ng, Chem. Commun., 2003, 1194 DOI: 10.1039/B301139A

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