Issue 11, 2003
From the journal:

Chemical Communications

Gold nanocluster confined within a cage: template-directed formation of a hexaporphyrin cage and its confinement capability

Tomohiko Inomataa  and  Katsuaki Konishi*a  

* Corresponding authors

a PRESTO, Japan Science and Technology Corporation (JST), and Division of Material Science, Graduate School of Environmental Earth Science, Hokkaido University, North 10 West 5, Sapporo 060-0810, Japan
E-mail: konishi@ees.hokudai.ac.jp
Fax: +81-11-706-4538

Abstract

A novel container complex in which a 1.4 nm gold cluster is confined within a hexaporphyrin cage was synthesized; the cage showed notable confinement capability for the cluster core, but allowed the interpenetration of small molecules into the interstitial space.

Graphical abstract: Gold nanocluster confined within a cage: template-directed formation of a hexaporphyrin cage and its confinement capability

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Article information

DOI
https://doi.org/10.1039/B302609D
Article type
Communication
Submitted
11 Mar 2003
Accepted
09 Apr 2003
First published
06 May 2003

Chem. Commun., 2003, 1282-1283

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Gold nanocluster confined within a cage: template-directed formation of a hexaporphyrin cage and its confinement capability

T. Inomata and K. Konishi, Chem. Commun., 2003, 1282 DOI: 10.1039/B302609D

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