Issue 38, 2003
From the journal:

CrystEngComm

A (10,3)-b net by sulfate hydrogen-bonded biimidazolate complexes

Krister Larssona  and  Lars Öhrström*b  

* Corresponding authors

a Department of Materials and Surface Chemistry, Chalmers Tekniska Högskola, Göteborg, Sweden
E-mail: kla@inoc.chalmers.se
Fax: +46 31 772 2846;
Tel: +46 31 772 2873

b Department of Materials and Surface Chemistry, Chalmers Tekniska Högskola, Göteborg, Sweden
E-mail: ohrstrom@inoc.chalmers.se
Fax: +46 31 772 2846
Tel: +46 31 772 2871

Abstract

The synthesis and crystal structure of Δ-[Cr(Hbiim)(H2biim)2]SO4·H2O (H2biim = biimidazole) are presented. A network is formed by sligthly distorted Δ-[Cr(Hbiim)(H2biim)2]2+ octahedra triple bridged by sulfate anions to give a (10,3)-b net. The final structure is given by three such interpenetrating nets, all with the same chirality on chromium. It is shown that the same net and interpenetration occur in [Fe(H2biim)3]CO3·MeOH.

Graphical abstract: A (10,3)-b net by sulfate hydrogen-bonded biimidazolate complexes

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Article information

DOI
https://doi.org/10.1039/B303107A
Article type
Paper
Submitted
18 Mar 2003
Accepted
19 May 2003
First published
02 Jun 2003

CrystEngComm, 2003,5, 222-225

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A (10,3)-b net by sulfate hydrogen-bonded biimidazolate complexes

K. Larsson and L. Öhrström, CrystEngComm, 2003, 5, 222 DOI: 10.1039/B303107A

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