Issue 11, 2003
From the journal:

Dalton Transactions

Pyridyl donor induced 1,3-silyl migration in metal complexes of the guanidine CyHNC{N(SiMe3)Py}NCy, Py = 2-(6-MeC5H3N)†‡

Marcus L. Colea  and  Peter C. Junk*a  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Vic 3800, Australia
E-mail: Peter.Junk@sci.monash.edu.au
Fax: +61(0)399054597
Tel: +61(0)399054570

Abstract

The insertion of 1,3-dicyclohexylcarbodiimide into a group 1 metallated 2-(trimethylsilyl)aminopyridine occurs with a 1,3-silyl shift of the intended guanidinate. An aluminium complex of the modified ligand, which exhibits pseudo β-diketiminate binding of the metal centre, exemplifies the coordinative versatility of this new multi N-donor system.

Graphical abstract: Pyridyl donor induced 1,3-silyl migration in metal complexes of the guanidine CyHNC{N(SiMe3)Py}NCy, Py = 2-(6-MeC5H3N)

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Article information

DOI
https://doi.org/10.1039/B303772J
Article type
Communication
Submitted
04 Apr 2003
Accepted
06 May 2003
First published
12 May 2003

Dalton Trans., 2003, 2109-2111

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Pyridyl donor induced 1,3-silyl migration in metal complexes of the guanidine CyHNC{N(SiMe3)Py}NCy, Py = 2-(6-MeC5H3N)

M. L. Cole and P. C. Junk, Dalton Trans., 2003, 2109 DOI: 10.1039/B303772J

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