Issue 5, 2004

Tin-free radical chemistry using the persistent radical effect: alkoxyamine isomerization, addition reactions and polymerizations

Abstract

In this tutorial review applications of alkoxyamines as C-radical precursors for the conduction of tin-free radical reactions are presented. These processes are controlled by the Persistent Radical Effect. A brief introduction on the Persistent Radical Effect is provided. In addition, the use of microwave irradiation to conduct thermal radical reactions is discussed. Finally, the use of alkoxyamines as initiators/mediators for the controlled/living radical polymerization is highlighted.

Graphical abstract: Tin-free radical chemistry using the persistent radical effect: alkoxyamine isomerization, addition reactions and polymerizations

Article information

Article type
Tutorial Review
Submitted
19 Dec 2003
First published
18 May 2004

Chem. Soc. Rev., 2004,033, 267-273

Tin-free radical chemistry using the persistent radical effect: alkoxyamine isomerization, addition reactions and polymerizations

A. Studer, Chem. Soc. Rev., 2004, 033, 267 DOI: 10.1039/B307652K

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