Issue 22, 2003
From the journal:

Chemical Communications

A rational synthetic route leading to 3d–3d′–4f heterospin systems: self-assembly processes involving heterobinuclear 3d–4f complexes and hexacyanometallates†

Ruxandra Gheorghe,a   Marius Andruh,*a   Jean-Pierre Costes*b  and  Bruno Donnadieub  

* Corresponding authors

a University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania
E-mail: marius.andruh@dnt.ro

b Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 4, France

Abstract

A novel heterospin system, [{CuL}Gd(H2O)3{Fe(CN)6}]·4H2O, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato groups with [Fe(CN)6]3− ions (L2− = N,N′-propylenedi(3-methoxysalicylideneiminato)).

Graphical abstract: A rational synthetic route leading to 3d–3d′–4f heterospin systems: self-assembly processes involving heterobinuclear 3d–4f complexes and hexacyanometallates

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Article information

DOI
https://doi.org/10.1039/B310082K
Article type
Communication
Submitted
21 Aug 2003
Accepted
26 Sep 2003
First published
17 Oct 2003

Chem. Commun., 2003, 2778-2779

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A rational synthetic route leading to 3d–3d′–4f heterospin systems: self-assembly processes involving heterobinuclear 3d–4f complexes and hexacyanometallates

R. Gheorghe, M. Andruh, J. Costes and B. Donnadieu, Chem. Commun., 2003, 2778 DOI: 10.1039/B310082K

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