Issue 1, 2004

Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Abstract

A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

Graphical abstract: Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
15 Sep 2003
Accepted
28 Oct 2003
First published
28 Nov 2003

Chem. Commun., 2004, 38-39

Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

A. Zapf, R. Jackstell, F. Rataboul, T. Riermeier, A. Monsees, C. Fuhrmann, N. Shaikh, U. Dingerdissen and M. Beller, Chem. Commun., 2004, 38 DOI: 10.1039/B311268N

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