Issue 4, 2004

A novel synthesis of chiral rotaxanesvia covalent bond formation

Abstract

Chiral rotaxanes composed of the asymmetric crownophane incorporating two hydroxy groups as a rotor moiety and the asymmetric axis were effectively synthesized via covalent bond formation, i.e. tandem Claisen rearrangement, esterification, and aminolysis.

Graphical abstract: A novel synthesis of chiral rotaxanes via covalent bond formation

Supplementary files

Article information

Article type
Communication
Submitted
14 Nov 2003
Accepted
07 Jan 2004
First published
28 Jan 2004

Chem. Commun., 2004, 466-467

A novel synthesis of chiral rotaxanes via covalent bond formation

N. Kameta, K. Hiratani and Y. Nagawa, Chem. Commun., 2004, 466 DOI: 10.1039/B314744D

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