Issue 6, 2004

The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)

Abstract

A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC–amide.

Graphical abstract: The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
11 Nov 2003
Accepted
19 Jan 2004
First published
13 Feb 2004

Chem. Commun., 2004, 698-699

The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(II)

R. E. Douthwaite, J. Houghton and B. M. Kariuki, Chem. Commun., 2004, 698 DOI: 10.1039/B314814A

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