A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

Daniel Maspoch; Daniel Ruiz-Molina; Klaus Wurst; Concepció Rovira; Jaume Veciana

doi:10.1039/B315147F

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A new (6³)·(6⁹.8¹) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical†

Daniel Maspoch,^a Daniel Ruiz-Molina,^a Klaus Wurst,^b Concepció Rovira^a and Jaume Veciana*^a

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* Corresponding authors

^a Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Catalonia, 08193 Bellaterra, Spain
E-mail: vecianaj@icmab.es
Fax: 34 93 5805729
Tel: 34 93 580 1853

^b Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a, A-6020, Austria

Abstract

The reaction of a 3-connecting PTMTC radical and a 2-connecting 4,4′-bipyridine ligands with Co(MeCOO)₂·4H₂O forms a paramagnetic non-interpenetrated supramolecular network, Co(PTMTC)(4,4′-bpy)(H₂O)₃·6EtOH·2H₂O (MOROF-2), with an unprecedented (6³)·(6⁹.8¹) topology exhibiting helical nanochannels.

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Article information

DOI: https://doi.org/10.1039/B315147F
Article type: Communication
Submitted: 24 Nov 2003
Accepted: 31 Mar 2004
First published: 22 Apr 2004

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Chem. Commun., 2004, 1164-1165

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A new (6³)·(6⁹.8¹) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

D. Maspoch, D. Ruiz-Molina, K. Wurst, C. Rovira and J. Veciana, Chem. Commun., 2004, 1164 DOI: 10.1039/B315147F

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