Issue 8, 2004
From the journal:

Chemical Communications

Elucidation of the mechanism of chiral selectivity in diastereomeric salt formation using organic solventnanofiltration

Nazlee F. Ghazali,a   Darrell A. Pattersona  and  Andrew G. Livingston*a  

* Corresponding authors

a Department of Chemical Engineering, Imperial College, Prince Consort Road, London, UK
E-mail: a.livingston@imperial.ac.uk
Fax: +442075945604
Tel: +442075945582

Abstract

Organic solvent nanofiltration (OSN) was used to investigate the mechanism of chiral selectivity in diastereomeric salt formation of α-phenylethylamine with D-tartaric acid and di-p-toluoyl-D-tartaric acid as resolving agents; results indicate that for these systems chiral selectivity occurs only upon crystallisation and chiral interactions in solution were negligible.

Graphical abstract: Elucidation of the mechanism of chiral selectivity in diastereomeric salt formation using organic solvent nanofiltration

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Article information

DOI
https://doi.org/10.1039/B400982G
Article type
Communication
Submitted
21 Jan 2004
Accepted
20 Feb 2004
First published
11 Mar 2004

Chem. Commun., 2004, 962-963

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Elucidation of the mechanism of chiral selectivity in diastereomeric salt formation using organic solvent nanofiltration

N. F. Ghazali, D. A. Patterson and A. G. Livingston, Chem. Commun., 2004, 962 DOI: 10.1039/B400982G

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