Issue 10, 2004

Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins

Abstract

Anchorage of PdII ions into mesoporous ion-exchange resins functionalized with sulfonic groups is highly effective for the direct synthesis of hydrogen peroxide using methanol as a solvent at 313 K. The high performance of these catalytic systems is due to the ability of sulfonic acid groups of the resin to interact and stabilize PdII ions without further reduction to metallic palladium, as revealed by photo-electron spectroscopy.

Graphical abstract: Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins

Article information

Article type
Communication
Submitted
19 Feb 2004
Accepted
29 Mar 2004
First published
22 Apr 2004

Chem. Commun., 2004, 1184-1185

Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins

G. Blanco-Brieva, E. Cano-Serrano, J. M. Campos-Martin and J. L. G. Fierro, Chem. Commun., 2004, 1184 DOI: 10.1039/B402530J

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