Issue 10, 2004
From the journal:

Chemical Communications

K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

Nan Ding,a   Duck-Young Chunga  and  Mercouri G. Kanatzidis*a  

* Corresponding authors

a Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA

Abstract

K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10−via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

Graphical abstract: K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

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Article information

DOI
https://doi.org/10.1039/B402686A
Article type
Communication
Submitted
20 Feb 2004
Accepted
22 Mar 2004
First published
23 Apr 2004

Chem. Commun., 2004, 1170-1171

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K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

N. Ding, D. Chung and M. G. Kanatzidis, Chem. Commun., 2004, 1170 DOI: 10.1039/B402686A

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