Issue 10, 2004
From the journal:

Dalton Transactions

Well-defined indium(iii) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst†

Jamie H. Cotgreave,a   David Colclough,b   Gabriele Kociok-Köhn,a   Giuseppe Ruggiero,a   Christopher G. Frost*a  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath

b GlaxoSmithKline, Old Powder Mills, Leigh, Nr Tonbridge, Kent
E-mail: c.g.frost@bath.ac.uk, a.s.weller@bath.ac.uk

Abstract

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

Graphical abstract: Well-defined indium(iii) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

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Article information

DOI
https://doi.org/10.1039/B404179H
Article type
Communication
Submitted
19 Mar 2004
Accepted
08 Apr 2004
First published
16 Apr 2004

Dalton Trans., 2004, 1519-1520

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Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

J. H. Cotgreave, D. Colclough, G. Kociok-Köhn, G. Ruggiero, C. G. Frost and A. S. Weller, Dalton Trans., 2004, 1519 DOI: 10.1039/B404179H

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