Issue 13, 2004

Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Abstract

Reaction of NO gas with sublimed layers of the MnIITPP (TPP = meso-tetraphenylporphyrinato2−) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-MnIII(TPP)(NO)(ONO).

Graphical abstract: Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Article information

Article type
Communication
Submitted
05 Mar 2004
Accepted
20 Apr 2004
First published
24 May 2004

Chem. Commun., 2004, 1488-1489

Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

G. G. Martirosyan, A. S. Azizyan, T. S. Kurtikyan and P. C. Ford, Chem. Commun., 2004, 1488 DOI: 10.1039/B404491F

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