Issue 15, 2004
From the journal:

Chemical Communications

Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+ (M = Ni(iii) or Pd(ii)) cores†

Nermeen W. Aboelella,a   John T. York,a   Anne M. Reynolds,a   Koyu Fujita,b   Christopher R. Kinsinger,a   Christopher J. Cramer,*a   Charles G. Riordan*b  and  William B. Tolman*a  

* Corresponding authors

a Department of Chemistry, Center for Metals in Biocatalysis, Supercomputer Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455
E-mail: tolman@chem.umn.edu, cramer@chem.umn.edu
Fax: 612-624-7029
Tel: 612-625-4061

b Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
E-mail: riordan@udel.edu
Fax: 302-831-6335
Tel: 302-831-1073

Abstract

Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

Graphical abstract: Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+ (M = Ni(iii) or Pd(ii)) cores

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Article information

DOI
https://doi.org/10.1039/B404640D
Article type
Communication
Submitted
30 Mar 2004
Accepted
10 Jun 2004
First published
29 Jun 2004

Chem. Commun., 2004, 1716-1717

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Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+ (M = Ni(III) or Pd(II)) cores

N. W. Aboelella, J. T. York, A. M. Reynolds, K. Fujita, C. R. Kinsinger, C. J. Cramer, C. G. Riordan and W. B. Tolman, Chem. Commun., 2004, 1716 DOI: 10.1039/B404640D

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