Issue 10, 2004
From the journal:

Dalton Transactions

Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(iii) units

Thomas A. Miller,a   John C. Jeffery,a   Michael D. Ward,*ab   Harry Adams,b   Simon J. A. Popec  and  Stephen Faulkner*c  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK

b Department of Chemistry, University of Sheffield, Sheffield, UK
E-mail: m.d.ward@sheffield.ac.uk

c Department of Chemistry, University of Manchester, Oxford Road, Manchester, UK
E-mail: Stephen.Faulkner@man.ac.uk

Abstract

Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2− with Yb(III) provides coordination polymers or oligomers containing Ru–CN–Yb bridges; in [K(H2O)4][Yb(H2O)6][Ru(bipy)(CN)4]2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s−1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.

Graphical abstract: Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(iii) units

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Article information

DOI
https://doi.org/10.1039/B404820B
Article type
Communication
Submitted
31 Mar 2004
Accepted
16 Apr 2004
First published
21 Apr 2004

Dalton Trans., 2004, 1524-1526

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Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(III) units

T. A. Miller, J. C. Jeffery, M. D. Ward, H. Adams, S. J. A. Pope and S. Faulkner, Dalton Trans., 2004, 1524 DOI: 10.1039/B404820B

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