Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipyip)(η2-CH2CHPh)][PF6] (bipyip = 6-isopropyl-2,2′-bipyridine)

Maria A. Cinellu; Giovanni Minghetti; Sergio Stoccoro; Antonio Zucca; Mario Manassero

doi:10.1039/B404890C

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Reaction of gold(iii) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF₆]. Crystal structure of [Au(bipy^ip)(η²-CH₂CHPh)][PF₆] (bipy^ip = 6-isopropyl-2,2′-bipyridine)†

Maria A. Cinellu,*^a Giovanni Minghetti,^a Sergio Stoccoro,^a Antonio Zucca^a and Mario Manassero^b

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* Corresponding authors

^a Dipartimento di Chimica, Università di Sassari, via Vienna 2, I-07100 Sassari, Italy
E-mail: cinellu@uniss.it

^b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano, Centro CNR, via Venezian 21, I-20133 Milano, Italy
E-mail: m.manassero@istm.cnr.it

Abstract

Gold alkene complexes [Au(bipy^R)(η²-alkene)][PF₆] (bipy^R = 6-alkyl-2,2′-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au₂(bipy^R)₂(μ-O)₂][PF₆]₂ with alkenes. The crystal structure of the styrene adduct [Au(bipy^ip)(η²-CH₂ [double bond, length as m-dash] CHPh)][PF₆] (bipy^ip = 6-isopropyl-2,2′-bipyridine) has been solved by X-ray analysis.

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Article information

DOI: https://doi.org/10.1039/B404890C
Article type: Communication
Submitted: 02 Apr 2004
Accepted: 21 May 2004
First published: 17 Jun 2004

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Chem. Commun., 2004, 1618-1619

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Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF₆]. Crystal structure of [Au(bipy^ip)(η²-CH₂CHPh)][PF₆] (bipy^ip = 6-isopropyl-2,2′-bipyridine)

M. A. Cinellu, G. Minghetti, S. Stoccoro, A. Zucca and M. Manassero, Chem. Commun., 2004, 1618 DOI: 10.1039/B404890C

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