Issue 19, 2004
From the journal:

Chemical Communications

Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes†

Yoshitaka Yamaguchi,*a   Taigo Kashiwabara,a   Kenichi Ogata,a   Yumiko Miura,a   Yoshiyuki Nakamura,b   Kimiko Kobayashic  and  Takashi Ito*a  

* Corresponding authors

a Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai, Yokohama 240-8501, Japan

b Chemical Resources Laboratory, Tokyo Institute of Technology, Nagatsuda, Yokohama 226-8503, Japan

c The Institute of Physical and Chemical Research (RIKEN), Hirosawa, Saitama 351-0198, Japan

Abstract

The reaction of an imidazolium salt with LiBEt3H afforded triethylborane adduct of imidazol-2-ylidene, which can act as a carbene precursor for the synthesis of a transition metal complex as well as a main group element complex.

Graphical abstract: Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes

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Article information

DOI
https://doi.org/10.1039/B405459H
Article type
Communication
Submitted
14 Apr 2004
Accepted
05 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2160-2161

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Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes

Y. Yamaguchi, T. Kashiwabara, K. Ogata, Y. Miura, Y. Nakamura, K. Kobayashi and T. Ito, Chem. Commun., 2004, 2160 DOI: 10.1039/B405459H

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