Issue 16, 2004
From the journal:

Chemical Communications

A new, practical access to amidyl radicals

Cécile Moutrille*a  and  Samir Z. Zarda  

* Corresponding authors

a Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France
E-mail: zard@poly.polytechnique
Fax: +33(0)169333851
Tel: +33 (0)169334872

Abstract

Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.

Graphical abstract: A new, practical access to amidyl radicals

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Article information

DOI
https://doi.org/10.1039/B405545D
Article type
Communication
Submitted
15 Apr 2004
Accepted
01 Jun 2004
First published
30 Jun 2004

Chem. Commun., 2004, 1848-1849

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A new, practical access to amidyl radicals

C. Moutrille and S. Z. Zard, Chem. Commun., 2004, 1848 DOI: 10.1039/B405545D

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