Issue 16, 2004

Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

Abstract

Bis-pinacolatodiboron reacts with α,β-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

Graphical abstract: Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

Article information

Article type
Communication
Submitted
23 Apr 2004
Accepted
26 May 2004
First published
30 Jun 2004

Chem. Commun., 2004, 1854-1855

Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

N. J. Bell, A. J. Cox, N. R. Cameron, J. S. O. Evans, T. B. Marder, M. A. Duin, C. J. Elsevier, X. Baucherel, A. A. D. Tulloch and R. P. Tooze, Chem. Commun., 2004, 1854 DOI: 10.1039/B406052K

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