Issue 15, 2004
From the journal:

Chemical Communications

Cruciform π-systems: effect of aggregation on emission†

James N. Wilson,a   Mark D. Smith,b   Volker Enkelmannc  and  Uwe H. F. Bunz*a  

* Corresponding authors

a School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, 770 State St, USA
E-mail: uwe.bunz@chemistry.gatech.edu
Fax: +1 404 385 1795
Tel: +1 404 385 1795

b Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA

c Max-Planck Institut für Polymerforschung, Mainz Postfach 3148, FRG

Abstract

The solid state properties of cruciform pentamers 1–4 are examined in thin film preparation, in the single crystalline state and in nanoparticle formulations; emission behavior was found to vary substantially with the solid state morphology. This type of behaviour is an excellent way to manipulate the emissive properties of conjugated π-systems.

Graphical abstract: Cruciform π-systems: effect of aggregation on emission

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Article information

DOI
https://doi.org/10.1039/B406495J
Article type
Communication
Submitted
16 Apr 2004
Accepted
25 May 2004
First published
28 Jun 2004

Chem. Commun., 2004, 1700-1701

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Cruciform π-systems: effect of aggregation on emission

J. N. Wilson, M. D. Smith, V. Enkelmann and U. H. F. Bunz, Chem. Commun., 2004, 1700 DOI: 10.1039/B406495J

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