Issue 14, 2004
From the journal:

Chemical Communications

Ligand-free Heck reactions using low Pd-loading

Manfred T. Reetza  and  Johannes G. de Vriesb  

a Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim/Ruhr, Germany

b DSM Pharma Chemicals, Advanced Synthesis, Catalysis & Development, PO box 18, 6160 MD Geleen, The Netherlands

Abstract

Activated and non-activated aryl bromides undergo smooth ligand-less Heck reactions, provided low amounts of palladium salts such as Pd(OAc)2 are used (ideally 0.01–0.1 mol%). This industrially viable process appears to involve palladium nanoparticles.

Graphical abstract: Ligand-free Heck reactions using low Pd-loading

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Article information

DOI
https://doi.org/10.1039/B406719N
Article type
Focus
First published
01 Jul 2004

Chem. Commun., 2004, 1559-1563

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Ligand-free Heck reactions using low Pd-loading

M. T. Reetz and J. G. de Vries, Chem. Commun., 2004, 1559 DOI: 10.1039/B406719N

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