Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements viaproton-induced reversible metal migration†
Abstract
Pairs of isomeric heterodinuclear complexes, [(cod)Ir(μ-PNNN)M(L)]BF4 and [(L)M(μ-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents.