Issue 21, 2004

Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene

Abstract

2-Chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb–Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene–SbCl3 complex.

Graphical abstract: Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene

Supplementary files

Article information

Article type
Communication
Submitted
25 Jun 2004
Accepted
05 Aug 2004
First published
22 Sep 2004

Chem. Commun., 2004, 2434-2435

Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene

D. Gudat, T. Gans-Eichler and M. Nieger, Chem. Commun., 2004, 2434 DOI: 10.1039/B409657F

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