Issue 20, 2004
From the journal:

Dalton Transactions

The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction†

Thomas Cadenbach,a   Christian Gemel,a   Rochus Schmid,a   Stefan Blockb  and  Roland A. Fischer*a  

* Corresponding authors

a Anorganische Chemie II, Ruhr Universität Bochum, Universitätsstrasse 150, Bochum, Germany
E-mail: roland.fischer@rub.de

b Anorganische Chemie I, Ruhr Universität Bochum, Universitätsstrasse 150, Bochum, Germany

Abstract

Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60 °C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

Graphical abstract: The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction

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Article information

DOI
https://doi.org/10.1039/B410077H
Article type
Communication
Submitted
02 Jul 2004
Accepted
19 Aug 2004
First published
31 Aug 2004

Dalton Trans., 2004, 3171-3172

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The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction

T. Cadenbach, C. Gemel, R. Schmid, S. Block and R. A. Fischer, Dalton Trans., 2004, 3171 DOI: 10.1039/B410077H

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