Issue 4, 2005
From the journal:

Dalton Transactions

Ionic radii for Group 1 halide crystals and ion-pairs†

Richard J. Collina  and  Barry C. Smith*b  

* Corresponding authors

a Cranleigh School, Cranleigh, Surrey, UK

b School of Biological and Chemical Sciences, Birkbeck College (University of London), Malet Street, London, UK
E-mail: smithbarryc@btinternet.com

Abstract

Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion-pairs appear to be anomalous. Soft-sphere ionic radii are compared with atomic radii of noble gases.

Graphical abstract: Ionic radii for Group 1 halide crystals and ion-pairs

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Article information

DOI
https://doi.org/10.1039/B410521B
Article type
Paper
Submitted
09 Jul 2004
Accepted
22 Dec 2004
First published
17 Jan 2005

Dalton Trans., 2005, 702-705

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Ionic radii for Group 1 halide crystals and ion-pairs

R. J. Collin and B. C. Smith, Dalton Trans., 2005, 702 DOI: 10.1039/B410521B

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