Issue 23, 2004
From the journal:

Chemical Communications

[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HC[triple bond, length as m-dash]CCPh2(OH)†

Victorio Cadierno,*a   Josefina Díez,a   Sergio E. García-Garridoa  and  José Gimeno*a  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica, I.U.Q.O.E.M. (Unidad Asociada al CSIC), Facultad de Química, Universidad de Oviedo, Oviedo, Spain
E-mail: jgh@uniovi.es (J. Gimeno); vcm@uniovi.es (V. Cadierno)
Fax: +34985103446
Tel: +34985103461

Abstract

The 16e− derivative [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.

Graphical abstract: [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HC [[triple bond, length as m-dash]] CCPh2(OH)

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Article information

DOI
https://doi.org/10.1039/B410812D
Article type
Communication
Submitted
15 Jul 2004
Accepted
07 Sep 2004
First published
14 Oct 2004

Chem. Commun., 2004, 2716-2717

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[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(II) catalyst for propargylic substitution and isomerization of HC[triple bond, length as m-dash]CCPh2(OH)

V. Cadierno, J. Díez, S. E. García-Garrido and J. Gimeno, Chem. Commun., 2004, 2716 DOI: 10.1039/B410812D

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