Issue 24, 2004
From the journal:

Chemical Communications

Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

Steven Stevenson,*a   J. Paige Phillips,b   Jon E. Reid,b   Marilyn M. Olmstead,c   Sankar Prasad Rathc  and  Alan L. Balch*c  

* Corresponding authors

a Department of Chemistry, University of Southern Mississippi, Hattiesburg, MS 39406-0001, USA
E-mail: Steven.Stevenson@usm.edu
Fax: (601)-266-6075
Tel: (601)-266-5142

b Luna Innovations, 2851 Commerce Street, Blacksburg, VA 24060, USA
E-mail: phillipsp@lunainnovations.com
Fax: (540)-951-0760
Tel: (540)-961-4529

c Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA
E-mail: albalch@ucdavis.edu
Fax: (530) 752 8995
Tel: (530) 752 0941

Abstract

The X-ray crystal structure of Gd3N@C80•NiII(OEP)•1.5(benzene) shows that the Gd3N unit within the Ih C80 cage is pyramidal, whereas Sc3N@C80, Sc3N@C78, Sc3N@C68, Lu3N@C80 and Sc2ErN@C80 have planar M3N units.

Graphical abstract: Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

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Article information

DOI
https://doi.org/10.1039/B412338G
Article type
Communication
Submitted
10 Aug 2004
Accepted
29 Oct 2004
First published
16 Nov 2004

Chem. Commun., 2004, 2814-2815

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Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

S. Stevenson, J. P. Phillips, J. E. Reid, M. M. Olmstead, S. P. Rath and A. L. Balch, Chem. Commun., 2004, 2814 DOI: 10.1039/B412338G

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