Issue 24, 2004
From the journal:

Chemical Communications

Crystal growth, defect structure and magnetism of new Li3N-derived lithium nitridocobaltates

Alexandra G. Gordon,a   Ronald I. Smith,b   Claire Wilson,a   Zlatka Stoevaa  and  Duncan H. Gregory*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: Duncan.Gregory@Nottingham.ac.uk
Fax: +44 (0)115 9513563
Tel: +44 (0)115 9514594

b ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, UK

Abstract

New nitridocobaltates Li3−x−yCoxN are revealed to contain significant Li+ vacancies (y ≈ 0.45) disordered within lithium–nitrogen planes and to exist as partially delocalised spin systems as a result of increased covalency through infinite –N–(Li,Co)–N– chains.

Graphical abstract: Crystal growth, defect structure and magnetism of new Li3N-derived lithium nitridocobaltates

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Article information

DOI
https://doi.org/10.1039/B413022G
Article type
Communication
Submitted
24 Aug 2004
Accepted
08 Oct 2004
First published
16 Nov 2004

Chem. Commun., 2004, 2812-2813

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Crystal growth, defect structure and magnetism of new Li3N-derived lithium nitridocobaltates

A. G. Gordon, R. I. Smith, C. Wilson, Z. Stoeva and D. H. Gregory, Chem. Commun., 2004, 2812 DOI: 10.1039/B413022G

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