Issue 4, 2005

Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands

Abstract

Tris(pyrazolyl)methanes are the neutral analogues of the widely exploited and highly useful tris(pyrazolyl)hydroborates, yet by comparison with their boron based counterparts their chemistry is underdeveloped. Recent breakthroughs in the synthesis of ring-substituted tris(pyrazolyl)methanes offer the opportunity for the development of this useful and promising class of ligand. This review summarises the current state of the coordination and organometallic chemistry of tris(pyrazolyl)methanes and highlights areas in which development is likely to occur.

Graphical abstract: Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands

Article information

Article type
Perspective
Submitted
26 Aug 2004
Accepted
08 Nov 2004
First published
18 Jan 2005

Dalton Trans., 2005, 635-651

Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands

H. R. Bigmore, S. C. Lawrence, P. Mountford and C. S. Tredget, Dalton Trans., 2005, 635 DOI: 10.1039/B413121E

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