Issue 1, 2005

The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

Abstract

Synthetic entry has been achieved into high oxidation state Mn–Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)2(OMe)2(O2CPh)18(H2O)4]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.

Graphical abstract: The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

Supplementary files

Article information

Article type
Communication
Submitted
07 Sep 2004
Accepted
11 Oct 2004
First published
25 Nov 2004

Chem. Commun., 2005, 54-56

The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis

A. Mishra, W. Wernsdorfer, K. A. Abboud and G. Christou, Chem. Commun., 2005, 54 DOI: 10.1039/B413680B

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