Issue 8, 2005
From the journal:

Chemical Communications

Synthesis and crystal structure of the first lanthanide complex of N-confused porphyrin with an η2 agostic C–H interaction†

Xunjin Zhu,a   Wai-Kwok Wong,*a   Wing-Kit Loa  and  Wai-Yeung Wonga  

* Corresponding authors

a Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong, P. R. China
E-mail: wkwong@hkbu.edu.hk

Abstract

The reaction of Ln[N(SiMe3)2]3·[LiCl(THF)3]x (Ln = Yb and Er) with N-confused tetraphenylporphyrin (H2NCTPP) followed by Na(LOMe) (LOMe = (η5-C5H5)Co[P([double bond, length as m-dash]O)(OMe)2]) gives (NCTPP)Ln(LOMe), whose X-ray structures exhibit an η2 agostic interaction between the metal centre and the inner C–H bond of the NCTPP ligand.

Graphical abstract: Synthesis and crystal structure of the first lanthanide complex of N-confused porphyrin with an η2 agostic C–H interaction

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Article information

DOI
https://doi.org/10.1039/B415609A
Article type
Communication
Submitted
11 Oct 2004
Accepted
25 Nov 2004
First published
05 Jan 2005

Chem. Commun., 2005, 1022-1024

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Synthesis and crystal structure of the first lanthanide complex of N-confused porphyrin with an η2 agostic C–H interaction

X. Zhu, W. Wong, W. Lo and W. Wong, Chem. Commun., 2005, 1022 DOI: 10.1039/B415609A

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