Synthesis and near infrared luminescence of a tetrametallic Zn2Yb2 architecture from a trinuclear Zn3L2 Schiff base complex

Xiaoping Yang; Richard A Jones; Vince Lynch; Michael M. Oye; Archie L. Holmes

doi:10.1039/B416695G

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Synthesis and near infrared luminescence of a tetrametallic Zn₂Yb₂ architecture from a trinuclear Zn₃L₂Schiff base complex†

Xiaoping Yang,^a Richard A Jones,*^a Vince Lynch,^a Michael M. Oye^bc and Archie L. Holmes^bc

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* Corresponding authors

^a The University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station A5300, Austin, TX 78712-0165, USA
E-mail: rajones@mail.utexas.edu
Tel: 512 471 6599

^b The University of Texas at Austin, 1 University Station Stop R9900, Austin, USA
Tel: 512 232 2735

^c Microelectronics Research Center and Texas Materials Institute, 1 University Station Stop R9900, Austin, TX 78712-0165, USA
Tel: 512 232 2735

Abstract

Near infrared luminescence is observed in tetrametallic [Zn₂Yb₂L₂(µ-OH)₂Cl₄]·2MeCN which is obtained from the Zn₃ Schiff-base complex [Zn₃L₂(NO₃)₂]·MeOH, (H₂L = N,N′-bis(5-bromo-3-methoxysalicylidene)propylene-1,3-diamine).

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Article information

DOI: https://doi.org/10.1039/B416695G
Article type: Communication
Submitted: 31 Oct 2004
Accepted: 21 Jan 2005
First published: 02 Feb 2005

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Dalton Trans., 2005, 849-851

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Synthesis and near infrared luminescence of a tetrametallic Zn₂Yb₂ architecture from a trinuclear Zn₃L₂ Schiff base complex

X. Yang, R. A. Jones, V. Lynch, M. M. Oye and A. L. Holmes, Dalton Trans., 2005, 849 DOI: 10.1039/B416695G

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Dalton Transactions