Issue 10, 2005
From the journal:

Chemical Communications

Fast and mild palladium(ii)-catalyzed 1,4-oxidation of 1,3-dienes viaactivation of molecular oxygen with a designed cobalt(ii) porphyrin†

Renzo C. Verboom,a   Vincent F. Slagta  and  Jan-E. Bäckvall*a  

* Corresponding authors

a Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
E-mail: jeb@organ.su.se
Fax: +46 8 154908
Tel: +46 8 6747178

Abstract

The use of a Co(porphyrin)-amide ligand, 2, in the palladium(II)-catalyzed 1,4-diacetoxylation of conjugated dienes under O2 results in aerobic oxidation. The catalyst was highly active under O2, and the 1,4-diacetoxylation reaction could also be performed under air.

Graphical abstract: Fast and mild palladium(ii)-catalyzed 1,4-oxidation of 1,3-dienes via activation of molecular oxygen with a designed cobalt(ii) porphyrin

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Article information

DOI
https://doi.org/10.1039/B417758D
Article type
Communication
Submitted
25 Nov 2004
Accepted
21 Dec 2004
First published
21 Jan 2005

Chem. Commun., 2005, 1282-1284

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Fast and mild palladium(II)-catalyzed 1,4-oxidation of 1,3-dienes via activation of molecular oxygen with a designed cobalt(II) porphyrin

R. C. Verboom, V. F. Slagt and Jan-E. Bäckvall, Chem. Commun., 2005, 1282 DOI: 10.1039/B417758D

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