Issue 5, 2005
From the journal:

Green Chemistry

Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex†

Shinsuke Kinoshita,a   Fumitoshi Shibahara‡b  and  Kyoko Nozaki*ab  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo-ku
E-mail: nozaki@chembio.t.u-tokyo.ac.jp
Fax: (+81)-3-5841-7261
Tel: (+81)-3-5841-7261

b Conversion and Control by Advanced Chemistry, PRESTO, Japan Science and Technology, 1-8, Honcho 4-Chome

Abstract

The difference between two methods for the synthesis of polystyrene-supported (R,S)-BINAPHOS-Rh(I) complex, namely (1) copolymerization of the monomeric ligand with divinylbenzene–ethylstyrene and then Rh-complex formation with the polymer-supported ligand, and (2) Rh-complex formation with the monomeric ligand and then immobilization of the Rh complex to polystyrene by copolymerization with divinylbenzene–ethylstyrene, is investigated by comparison of their catalytic performance, by surface analysis and particle-size measurement.

Graphical abstract: Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex

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Article information

DOI
https://doi.org/10.1039/B418264B
Article type
Communication
Submitted
08 Dec 2004
Accepted
01 Mar 2005
First published
21 Mar 2005

Green Chem., 2005,7, 256-258

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Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex

S. Kinoshita, F. Shibahara and K. Nozaki, Green Chem., 2005, 7, 256 DOI: 10.1039/B418264B

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