Issue 22, 2005
From the journal:

Chemical Communications

The remarkable efficiency of N-heterocyclic carbenes in lanthanide(iii)/actinide(iii) differentiation

Thouraya Mehdoui,a   Jean-Claude Berthet,*a   Pierre Thuérya  and  Michel Ephritikhine*a  

* Corresponding authors

a Service de Chimie Moléculaire, DSM, DRECAM, CNRS URA 331, CEA Saclay, Gif-sur-Yvette, France
E-mail: ephri@drecam.cea.fr, berthet@drecam.cea.fr
Fax: +33(0)169086640
Tel: +33(0)169086436

Abstract

The capacity of NHC molecules to discriminate between trivalent lanthanide and actinide ions was revealed by competition reactions of analogous U(III) and Ce(III) compounds with C3Me4N2 and a comparison of the crystal structures of the corresponding carbene adducts.

Graphical abstract: The remarkable efficiency of N-heterocyclic carbenes in lanthanide(iii)/actinide(iii) differentiation

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Article information

DOI
https://doi.org/10.1039/B503526K
Article type
Communication
Submitted
10 Mar 2005
Accepted
08 Apr 2005
First published
22 Apr 2005

Chem. Commun., 2005, 2860-2862

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The remarkable efficiency of N-heterocyclic carbenes in lanthanide(III)/actinide(III) differentiation

T. Mehdoui, J. Berthet, P. Thuéry and M. Ephritikhine, Chem. Commun., 2005, 2860 DOI: 10.1039/B503526K

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