Issue 27, 2005
From the journal:

Chemical Communications

Synthesis of a four-coordinate titanium(iv) oxoanionvia deprotonation and decarbonylation of complexed formate†‡

Arjun Mendiratta,a   Joshua S. Figueroaa  and  Christopher C. Cummins*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Room 2-227, Cambridge, USA
E-mail: ccummins@mit.edu
Fax: +1 617 258 5700
Tel: +1 617 253 5332

Abstract

Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.

Graphical abstract: Synthesis of a four-coordinate titanium(iv) oxoanion via deprotonation and decarbonylation of complexed formate

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Article information

DOI
https://doi.org/10.1039/B504492H
Article type
Communication
Submitted
31 Mar 2005
Accepted
16 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3403-3405

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Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate

A. Mendiratta, J. S. Figueroa and C. C. Cummins, Chem. Commun., 2005, 3403 DOI: 10.1039/B504492H

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