Issue 28, 2005
From the journal:

Chemical Communications

Highly enantioselective iridium-catalysed allylic aminations with anionic N-nucleophiles†

Robert Weihofen,a   Axel Dahnz,a   Olena Tverskoya  and  Günter Helmchen*a  

* Corresponding authors

a Organisch-Chemisches Institut der Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69207 Heidelberg, Germany
E-mail: g.helmchen@urz.uni-heidelberg.de
Fax: +49 6221 544205
Tel: +49 6221 548401

Abstract

Iridium-catalysed allylic substitutions with anionic N-nucleophiles were achieved with regioselectivity of up to 49∶1 and enantiomeric excess of up to 98%.

Graphical abstract: Highly enantioselective iridium-catalysed allylic aminations with anionic N-nucleophiles

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Article information

DOI
https://doi.org/10.1039/B505197E
Article type
Communication
Submitted
13 Apr 2005
Accepted
11 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3541-3543

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Highly enantioselective iridium-catalysed allylic aminations with anionic N-nucleophiles

R. Weihofen, A. Dahnz, O. Tverskoy and G. Helmchen, Chem. Commun., 2005, 3541 DOI: 10.1039/B505197E

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