Issue 26, 2005
From the journal:

Chemical Communications

First osmium-catalysed ketamination of alkenes†

Amparo Villar,a   Claas H. Hövelmann,a   Martin Niegerb  and  Kilian Muñiz*a  

* Corresponding authors

a Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, Germany
E-mail: kilian.muniz@uni-bonn.de
Fax: +49 228 735813
Tel: +49 228 736553

b Institut für Anorganische Chemie, Gerhard-Domagk-Str. 1, Germany
E-mail: nieger@joyx.joensuu.fi

Abstract

Conditions for a first oxidative conversion of alkenes into 2-amino ketones are described, which yield racemic products within a direct oxidation pathway and 2-amino ketones with up to 99% enantiomeric excess from the corresponding enantiopure amino alcohols.

Graphical abstract: First osmium-catalysed ketamination of alkenes

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Article information

DOI
https://doi.org/10.1039/B505278P
Article type
Communication
Submitted
14 Apr 2005
Accepted
16 May 2005
First published
01 Jun 2005

Chem. Commun., 2005, 3304-3306

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First osmium-catalysed ketamination of alkenes

A. Villar, C. H. Hövelmann, M. Nieger and K. Muñiz, Chem. Commun., 2005, 3304 DOI: 10.1039/B505278P

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