Issue 36, 2005
From the journal:

Chemical Communications

Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands†‡

Philip J. Bailey,*a   Robert A. Coxall,a   Caroline M. Dick,a   Sylvie Fabre,a   Simon Parsonsa  and  Lesley J. Yellowleesa  

* Corresponding authors

a Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: Philip.Bailey@ed.ac.uk

Abstract

Treatment of dimethylmagnesium with bulky α-diimine ligands provides either the biradical methyl-bridged complexes [(α-diimine−˙)Mg+(μ-CH3)]2via single electron transfer (SET), or the product of methyl transfer to an imine carbon atom depending upon conditions.

Graphical abstract: Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands

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Article information

DOI
https://doi.org/10.1039/B505697G
Article type
Communication
Submitted
25 Apr 2005
Accepted
22 Jul 2005
First published
17 Aug 2005

Chem. Commun., 2005, 4563-4565

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Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands

P. J. Bailey, R. A. Coxall, C. M. Dick, S. Fabre, S. Parsons and L. J. Yellowlees, Chem. Commun., 2005, 4563 DOI: 10.1039/B505697G

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