Issue 23, 2005

Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(iv) and pentacyanocobaltate(ii)

Abstract

Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2− and [Co(CN)5]3−, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.

Graphical abstract: Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(iv) and pentacyanocobaltate(ii)

Article information

Article type
Paper
Submitted
01 Jun 2005
Accepted
05 Aug 2005
First published
02 Sep 2005

Dalton Trans., 2005, 3814-3817

Structural investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II)

S. Diaz-Moreno, D. T. Bowron and J. Evans, Dalton Trans., 2005, 3814 DOI: 10.1039/B507738A

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