Issue 17, 2005
From the journal:

Dalton Transactions

A highly water-soluble platinum(ii) complex containing a thiopropyl-1,2-dicarba-closo-dodecaborane(12) ligand functionalised with a pendant glycerol group†

Ellen L. Crossley,a   Daniela Caiazza‡b  and  Louis M. Rendina*a  

* Corresponding authors

a School of Chemistry, The University of Sydney, Sydney, NSW, Australia
E-mail: rendina@chem.usyd.edu.au
Fax: +61 2 9351 3329
Tel: +61 2 9351 4781

b School of Chemistry and Physics, The University of Adelaide, Adelaide, SA, Australia

Abstract

Reaction of the novel thiopropyl-closo-1,2-carborane ligand bearing a pendant glycerol group HS(CH2)3CB10H10CCH2OCH(CH2OH)2 (L) with the labile platinum(II) precursor [Pt(MeCN)(terpy)](OTf)2 (terpy = 2,2′:6′,2″-terpyridine; OTf = trifluoromethanesulfonate) affords the highly water-soluble platinum(II) complex [PtL(terpy)]OTf, the first example of a metal–carborane complex functionalised with a water-solubilising glycerol group.

Graphical abstract: A highly water-soluble platinum(ii) complex containing a thiopropyl-1,2-dicarba-closo-dodecaborane(12) ligand functionalised with a pendant glycerol group

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Article information

DOI
https://doi.org/10.1039/B508020G
Article type
Communication
Submitted
09 Jun 2005
Accepted
07 Jul 2005
First published
20 Jul 2005

Dalton Trans., 2005, 2825-2826

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A highly water-soluble platinum(II) complex containing a thiopropyl-1,2-dicarba-closo-dodecaborane(12) ligand functionalised with a pendant glycerol group

E. L. Crossley, D. Caiazza and L. M. Rendina, Dalton Trans., 2005, 2825 DOI: 10.1039/B508020G

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