Visible light-induced selective oxidation of cyclohexane to cyclohexanone on Cr–Si binary oxide with molecular oxygen

Yasuhiro Shiraishi; Yugo Teshima; Takayuki Hirai

doi:10.1039/B508172F

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Visible light-induced selective oxidation of cyclohexane to cyclohexanone on Cr–Si binary oxide with molecular oxygen†

Yasuhiro Shiraishi,*^a Yugo Teshima^a and Takayuki Hirai^a

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* Corresponding authors

^a Research Center for Solar Energy Chemistry, and Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka, Japan
E-mail: shiraish@cheng.es.osaka-u.ac.jp
Fax: +81-6-6850-6273
Tel: +81-6-6850-6271

Abstract

Cr–Si binary oxide prepared by a sol–gel method, when activated by visible light, catalyses highly selective oxidation of cyclohexane to cyclohexanone with molecular oxygen.

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Supplementary files

Experimental details; change in product yield with time when cyclohexane (Fig. S1) or cyclohexanone (Fig. S2) is used as a starting material; ESR spectra (Fig. S3); N ₂ adsorption-desorption isotherm of catalyst (Fig. S4) PDF (228K)

Article information

DOI: https://doi.org/10.1039/B508172F
Article type: Communication
Submitted: 09 Jun 2005
Accepted: 15 Jul 2005
First published: 17 Aug 2005

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Chem. Commun., 2005, 4569-4571

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Visible light-induced selective oxidation of cyclohexane to cyclohexanone on Cr–Si binary oxide with molecular oxygen

Y. Shiraishi, Y. Teshima and T. Hirai, Chem. Commun., 2005, 4569 DOI: 10.1039/B508172F

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Chemical Communications

Visible light-induced selective oxidation of cyclohexane to cyclohexanone on Cr–Si binary oxide with molecular oxygen†

Abstract

Supplementary files

Article information

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Visible light-induced selective oxidation of cyclohexane to cyclohexanone on Cr–Si binary oxide with molecular oxygen

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