Issue 37, 2005
From the journal:

Chemical Communications

Diastereoselective formation and optical activity of an M4L6 cage complex

Stephen P. Argent,a   Thomas Riis-Johannessen,b   John C. Jeffery,b   Lindsay P. Hardingc  and  Michael D. Ward*a  

* Corresponding authors

a Department of Chemistry, University of Sheffield, Sheffield, UK S3 7HF
E-mail: m.d.ward@Sheffield.ac.uk
Fax: +44 (0)114 2229484
Tel: +44 (0)114 2229346

b School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS

c Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK HD1 3DH

Abstract

A chiral bridging ligand affords a single diastereoisomer of tetrahedral M4L6 cage complex in which the optical rotation of each ligand is increased by a factor of 5 on coordination.

Graphical abstract: Diastereoselective formation and optical activity of an M4L6 cage complex

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Article information

DOI
https://doi.org/10.1039/B509239F
Article type
Communication
Submitted
30 Jun 2005
Accepted
09 Aug 2005
First published
17 Aug 2005

Chem. Commun., 2005, 4647-4649

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Diastereoselective formation and optical activity of an M4L6 cage complex

S. P. Argent, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding and M. D. Ward, Chem. Commun., 2005, 4647 DOI: 10.1039/B509239F

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