Issue 89, 2005
From the journal:

CrystEngComm

Solventhydrolysis and templating effects in the synthesis of metal–organic frameworks

Andrew D. Burrows,*a   Kevin Cassar,a   Richard M. W. Friend,a   Mary F. Mahon,a   Sean P. Rigbyb  and  John E. Warrenc  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: a.d.burrows@bath.ac.uk

b Department of Chemical Engineering, University of Bath, Claverton Down, Bath, UK

c CLRC Daresbury Laboratory, Daresbury, Warrington, UK

Abstract

Hydrolysis of the DMF or DEF solvent influences the nature of the product observed in the reaction between zinc(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks.

Graphical abstract: Solvent hydrolysis and templating effects in the synthesis of metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/B509460G
Article type
Communication
Submitted
05 Jul 2005
Accepted
04 Aug 2005
First published
12 Aug 2005

CrystEngComm, 2005,7, 548-550

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Solvent hydrolysis and templating effects in the synthesis of metal–organic frameworks

A. D. Burrows, K. Cassar, R. M. W. Friend, M. F. Mahon, S. P. Rigby and J. E. Warren, CrystEngComm, 2005, 7, 548 DOI: 10.1039/B509460G

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