Issue 40, 2005
From the journal:

Chemical Communications

Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel†‡

Vlad M. Iluc,a   Alexander J. M. Millera  and  Gregory L. Hillhouse*a  

* Corresponding authors

a Searle Chemistry Laboratory, Department of Chemistry, The University of Chicago, 5735 S. Ellis Ave., Chicago, USA
E-mail: g-hillhouse@uchicago.edu
Fax: 773-702-0805
Tel: 773-702-7057

Abstract

Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and end-on coordination of the NO ligand.

Graphical abstract: Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel

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Article information

DOI
https://doi.org/10.1039/B510131J
Article type
Communication
Submitted
15 Jul 2005
Accepted
17 Aug 2005
First published
15 Sep 2005

Chem. Commun., 2005, 5091-5093

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Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel

V. M. Iluc, A. J. M. Miller and G. L. Hillhouse, Chem. Commun., 2005, 5091 DOI: 10.1039/B510131J

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