Issue 43, 2005
From the journal:

Chemical Communications

Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond†

Nicholas J. Hill,a   Jennifer A. Moore,a   Michael Findlatera  and  Alan H. Cowley*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas, USA
E-mail: cowley@mail.utexas.edu
Fax: (+1) 512-471-6822
Tel: (+1) 512-471-7484

Abstract

A 1 ∶ 1 Lewis acid–base complex between CyN[double bond, length as m-dash]C[double bond, length as m-dash]NCy and PhBCl2 has been isolated and structurally characterized, heating of which in refluxing toluene results in the amidinate, [PhC{NCy}2]BCl2; the overall reaction has been modeled by DFT calculations.

Graphical abstract: Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond

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Article information

DOI
https://doi.org/10.1039/B511080G
Article type
Communication
Submitted
03 Aug 2005
Accepted
13 Sep 2005
First published
03 Oct 2005

Chem. Commun., 2005, 5462-5464

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Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond

N. J. Hill, J. A. Moore, M. Findlater and A. H. Cowley, Chem. Commun., 2005, 5462 DOI: 10.1039/B511080G

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